Hello,
There is no point performing haphazard measuring and planning changes based on the results. You'll need to dedicate time and patience to optimizing your methods. In-line devices are generally more effective than in-tank devices. The only reason I could think of where the reverse is true would be if the inlet spud of your in-line device has a smaller diameter than your filter outlet spud or if the filter return line is somehow restricted.
You need to step back and take a deep breath. Whatever method you used to get the tank to the state is is in the photo you showed in post number 8 is clearly valid, so I don't see any need to start dismantling things.
Thanks become victims of their own success. You could easily perform some pruning and free up some space for flow and that alone would be a good solution.
If you don't want to do that then you simply need to find a day you can dedicate to experimenting with the injection rate so that you get a good pH drop by lights on but that does not continue to saturate the water with so much CO2 that you cause discomfort to the fish. That will fine tune the CO2. Clean the filter and remove some media if it is chock full of media. That will improve your flow rate. Usually, only small changes are required to support continued growth and health.
Cheers,