Hi all,
. I know it degasses the tank from co2 but what if you had no co2 in the tank? would it still be pointless?
I only added an air stone as the discus seemed to breathe more rapidly without it. Im reconfiguring my co2 setup on sunday as im in all day so i will remive the air stone and see what effect it has on the fish and re calibrate my co2 to compensate.
There is a huge difference in level between adding CO2 and it diffusing in via gas exchange from the atmosphere.
If we aren't adding CO2 it is better to have as much gas exchange as possible in both terms of CO2 and O2 levels. Wet and dry trickle filters are most effective for doing this, but an air stone, or lots of flow, all work.
Have a look here: "
Aeration and dissolved oxygen in the aquarium" - <
plecoplanet: Aeration and dissolved oxygen in the aquarium>, I wrote it for plec keepers, but the principles are the same for any fish keeping.
CO2 is very complicated and I think people grossly underestimate it's level of difficulty.
I'll have a go at this, but it may need some corrections:
CO2
CO2 makes up 0.0355% of the atmosphere (~355ppm).
When CO2 is dissolved in water a fraction of it forms carbonic acid H2CO3 (CO2 (aq) + H2O « H2CO3 (aq)) and it really is a small fraction, about 1.3 x10-3 of the (so just over 1/1000) of the dissolved CO2. We also have the carbonate - CO2 equilibria (K1 & K2), when carbonate buffering is present in the water:
K1 =
H2CO3 (aq) « H+ (aq) + HCO3- (aq).
K2 =
HCO3- (aq) « H+ (aq) + CO32- (aq)
Adding CO2
Our drop checkers use both the proportion of carbonic acid and the carbonate equilibria to give us a measure of pH and CO2 level, from the pH/ kH/ CO2 chart
<
ShrimpNow !!! - Water Parameters: Understanding pH, GH, KH and others>
Drop Checker
When we add CO2 this means that the carbonate equilibrium is not now with ambient levels of CO2, but with the amount of CO2 that we are adding. It is the depression of pH (caused by the small proportion of H2CO3) that is causing the bromothymol blue pH indicator <
Bromothymol blue - Wikipedia, the free encyclopedia> in the 4dKH solution in the drop checker to change colour (to green or yellow). When we stop adding CO2 the CO2/carbonate equilibria will re-equilibrate with atmospheric CO2 levels, H2CO3 levels will fall, and the pH will rise, and the drop checker turn back to blue (>pH7.6). The pH will rise above pH7 due to the alkalinity (carbonate buffering) of the 4dKH solution in the drop checker.
Natural CO2 levels in tank water
The natural level of CO2 in water will depend upon the size of the gas exchange surface, temperature of the water, pH and the balance between plants and animals during the photo-period. If we look at water with low carbonate buffering we are looking at about 0.5ppm CO2 at 25oC, (CO2 details in <
CHEMICAL FEATURES OF WATER>). If we have a high fish load, a heavily planted tank and a small gas exchange surface, levels may rise to 10 - 15ppm before lights on. In the same scenario, during the photo-period, when the plants are photosynthesising, CO2 levels are likely to be um-measurably small. I won't talk any more about dissolved oxygen (O2), but the details are here (they are different links): <
CHEMICAL FEATURES OF WATER>.
If we have very efficient gas exchange it helps both ways by reducing the variation in CO2 and O2 levels, it is a win win situation.
cheers Darrel