My guess as well, and probably NaOH, they add it to nearly all soft water in the UK to raise the pH (they also add PO4---, but that isn't such a strong base).So your 5KH could be an artefactually high reading, caused by eg NaOH or phosphate in the water, and that is neutralised in the tank. KH of 1 being nearer the truth.
That would be my guess anyway