Hi all,
It won't do any harm, but it doesn't need to be charcoal, and it definitely doesn't need to be tourmaline. Adsorbent material like activated carbon (and to a lesser degree charcoal) hold other molecules via the weak physical "Van Der Waal" forces, but humic or clay compounds have a high CEC (Cation Exchange Capacity), and are potentially much more useful. Humic substances will also have
AEC (Anion Exchange Capacity) under acidic conditions. Cation Exchange Capacity is the relative number of negatively charged binding sites on the surfaces of a substance (which bind positively charged ions cations like Mg++), the amount and nature of the cation bonding depends upon the lyotropic series. Anions are negatively charged ions like NO3-.
It won't make any difference. Any substrate layer, other than a very thin gravel one, will have fluctuating aerobic and anaerobic zones, but this isn't a problem. Have a look at these links <
Substrate | The Skeptical Aquarist> & <
Humic substances | The Skeptical Aquarist>.
cheers Darrel