This true for terrestrial plants, but is it true for aquatics? These plants are very leaky and potassium is not bound in the plant so it can enter or leave.
Excuse me, but it's a very simplistic position. I believe you've got it from an old post by
@ceg4048 . Most of the potassium within a plant is in ionic form, in solutions, that's true. But majority of K is inside the plant's cells, even in organelles and vacuoles. Do you think that ANY ion can get there or out by a mere diffusion?
Of course not. From vacuole to outer environment, any ion must pass multiple "checkpoints" - membranes, guarded by specific proteins, through which the transport is controlled, mostly electro-chemically, actively, and as such,
requiring energy input. It truly makes little difference if behind the last checkpoint there is an air or water.
The plants as such are NOT very leaky, and in most cases, they must spend energy when they want to get something in or out. They could not survive if they were "leaky" and depended on mere concentration gradient, that's a nonsense.