Hi Mark, do you know what the total alkalinity / carbonates are of the tap water you are using to do the water changes? I read you said a hardness of 6dH, but do you know the kH / ppm CaCO3 from the water provider? (can get a water report from their website and is really revealing regarding ferts and effectiveness of test kits etc).
Pretty sure Garuf has nailed it with the biogenic decalcification hunch, each Friday with your water change you are providing a big dose of carbon in the bicarbonate form that certain plants will, if given enough light energy / lack of CO2, be able to strip down to CO2, the downside is the white calcium carbonate deposits on the leaves - they go kinda crusty! I've had it on loads on my plants - seen it on Cryptocorynes, Cyperus Helferi, Echinodorus, etc (my tapwater has 185ppm Calcium Carbonate), not all plants can do this and it's an adaptation that works for plants coming from hardwaters.
I'm not seeing carbon deficiency so much as carbonate efficiency by certain plants...and the algae.
Solutions:-
1.lower light (regrow the salvinia?) as per Clive's original suggestion...dissolved CO2 at current concentrations will match the rate of photosynthesis, without plants / pulling on the carbonates for food.
2.Lower carbonate going into tank (mix with rainwater / RO)...will mean you can add same level of CO2 as current, but have a greater percent in solution as simple dissolved CO2.
3. Dance a finer line with injecting more CO2, and most importantly, inject when the plants most need it, so that the carbonate reserves aren't dipped into by the plants, as was also suggested.
4. Lower the frequency of water changes, inject the same level of CO2, so that the alkalinity slowly falls with the removal of crusty leaves, and maintain a lower carbonate, essentially living with it. Will mean adjusting fert parameters / monitoring the buffering capacity of the remaining carbonate reserves, etc.
I think all these things are the Catch 22 of hard tap water, but at least your plants are growing and you care for the wellbeing in the tank, so it's a challenge rather than a disaster.
I hope you find a solution that works for you
regards
Gary