The thing with liquid carbon is that it only has a maximum of 24hr active life once in the aquarium before it is either used up by your plants or broken down into ineffective compounds. If you put 6ml in one day, then leave it for three days, then your plants are getting a huge hit of carbon for the first 24hrs, then going hungry for the rest of the time.....additionally it is more likely to have a detrimental effect on livestock overdosing in such a way. There is also no benefit to having a rest day with carbon either as you cannot build up an excess as with pressurised it gasses off continuously, and with liquid products it has a shelf life in the water. I'm sure if you offered less, but every day things would improve further for you. You just need to get the right amount to feed their needs. I'd start at double the recommended dosage on your mature systems.
Here's a nice synopsis of liquid carbon from Richard at Aquaessentials:
Liquid Carbon in a planted aquarium | The Planted Aquarium Blog
Having said all that, if your tanks are working for you then happy days, but do you not also dose carbonated water to boost co2? This could be helping the plants get the extra carbon......what days do you add the carbonated water, consistently, the days you don't dose liquid carbon?
Cheerio,