Around my area which is not far from the ardennes, is it a very common rock to find.. I'm using it already for months also on my latest non co2 tank..
It's indeed a calcite and it reacts heavily if put in acid. I also researched about them and because they are very common to find in a large triangle from Ardennes - Belgium, Nortrhein Westfalen - Germany to Limburg - The Netherlands. You'll find most information about these rocks on forums from these countries. Anyway remarkably enough even if these stones are calcite i only did read positive experiences from people using them and it seems this rock is still very stable in water and not realy affecting the water quality in a drastic way.
I still did put it to the test in a planted only tank and indeed i must confirm, even after 4 weeks no water change with relatively medium to soft water pH 7 to 8, dKh 4 and dGh 4 i didn't notice any changes to these tests. After that i tested again a few times with the regular 25% water change per 2 weeks it just stays stable. In a planted tank with life stock you might do waterchanges more often.
Even did do a regular test with adding phosporic acid to lower the pH, it didn't change.. But must say, using acid the lower Ph is not for long term.. I didn't test it with long term adding Co2.
But with the regular water changes i do not expect problems here..
This is the test setup and had it running for about 5 to 6 months..
So far in the above described intervals i didn't notice any negative effects.. And since i do regular water changes anyway there is no need to be afraid of this rock.
The acid test indeed is a good way to find out if the rock contains any kind of lime and it's also a good practice to skip these kinds of rocks if you have no means to test them for longer periode. But confirmed the test doesn't mean in particular that all to acid reacting rocks are unsuitable. Ardennes Rock certainly is suitable for non co2 aquarium use if they leach anything it's rather so slow it doesn't affect notably, maybe on a very long term without water changes..